by Benoξt Dubι and Patrice Gosselin
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Greenstone-hosted quartz-carbonate vein deposits typically occur in deformed greenstone belts of all ages, especially those with variolitic tholeiitic basalts and ultramafic komatiitic flows intruded by intermediate to felsic porphyry intrusions, and sometimes with swarms of albitite or lamprophyre dyke. They are distributed along major compressional to transtensional crustal-scale fault zones in deformed greenstone terranes commonly marking the convergent margins between major lithological boundaries, such as volcano-plutonic and sedimentary domains. The large greenstonehosted quartz-carbonate vein deposits are commonly spatially associated with fluvio-alluvial conglomerate (e.g. Timiskaming conglomerate) distributed along major crustal fault zones (e.g. Destor Porcupine Fault). This association suggests an empirical time and space relationship between large-scale deposits and regional unconformities.
These types of deposits are most abundant and significant, in terms of total gold content, in Archean terranes. However, a significant number of world-class deposits are also found in Proterozoic and Paleozoic terranes. In Canada, they represent the main source of gold and are mainly located in the Archean greenstone belts of the Superior and Slave provinces. They also occur in the Paleozoic greenstone terranes of the Appalachian orogen and in the oceanic terranes of the Cordillera.
The greenstone-hosted quartz-carbonate vein deposits correspond to structurally controlled complex epigenetic deposits characterized by simple to complex networks of gold-bearing, laminated quartz-carbonate fault-fill veins. These veins are hosted by moderately to steeply dipping, compressional brittle-ductile shear zones and faults with locally associated shallow-dipping extensional veins and hydrothermal breccias. The deposits are hosted by greenschist to locally amphibolite-facies metamorphic rocks of dominantly mafic composition and formed at intermediate depth (5- 10 km). The mineralization is syn- to late-deformation and typically post-peak greenschist -facies or syn-peak amphibolite- facies metamorphism. They are typically associated with iron-carbonate alteration. Gold is largely confined to the quartz-carbonate vein network but may also be present in significant amounts within iron-rich sulphidized wall-rock selvages or within silicified and arsenopyrite-rich replacement zones.
There is a general consensus that the greenstone-hosted quartz-carbonate vein deposits are related to metamorphic fluids from accretionary processes and generated by prograde metamorphism and thermal re-equilibration of subducted volcano-sedimentary terranes. The deep-seated, Au-transporting metamorphic fluid has been channelled to higher crustal levels through major crustal faults or deformation zones. Along its pathway, the fluid has dissolved various components - notably gold - from the volcano-sedimentary packages, including a potential gold-rich precursor. The fluid then precipitated as vein material or wall-rock replacement in second and third order structures at higher crustal levels through fluid-pressure cycling processes and temperature, pH and other physico-chemical variations.
Simplified Definition
Greenstone-hosted quartz-carbonate vein deposits occur as quartz and quartz-carbonate veins, with valuable amounts of gold and silver, in faults and shear zones located within deformed terranes of ancient to recent greenstone belts commonly metamorphosed at greenschist facies.
Scientific Definition
Greenstone-hosted quartz-carbonate vein deposits are a subtype of lode gold deposits (Poulsen et al., 2000) (Fig. 1). They are also known as mesothermal, orogenic (mesozonal and hypozonal - the near surface orogenic epizonal Au-Sb-Hg deposits described by Groves et al. (1998) are not included in this synthesis), lode gold, shear-zone-related quartzcarbonate or gold-only deposits (Hodgson and MacGeehan, 1982; Roberts, 1987; Colvine, 1989; Kerrich and Wyman, 1990; Robert, 1990; Kerrich and Feng, 1992; Hodgson, 1993; Kerrich and Cassidy, 1994; Robert, 1995; Groves et al., 1998; Hagemann and Cassidy, 2000; Kerrich et al., 2000; Poulsen et al., 2000; Goldfarb et al., 2001; Robert and Poulsen, 2001; Groves et al., 2003; Goldfarb et al., 2005; Robert et al., 2005). The focus of the following text is mainly on Canadian examples and particularly those deposits found in the Abitibi Archean greenstone belt. For a complete global perspective, readers are referred to the above list of selected key references.
Greenstone-hosted quartz-carbonate vein deposits are structurally controlled, complex epigenetic deposits that are hosted in deformed and metamorphosed terranes. They consist of simple to complex networks of gold-bearing, laminated quartz-carbonate fault-fill veins in moderately to steeply dipping, compressional brittle-ductile shear zones and faults, with locally associated extensional veins and hydrothermal breccias. They are dominantly hosted by mafic metamorphic rocks of greenschist to locally lower amphibolite facies and formed at intermediate depths (5-10 km). Greenstone-hosted quartz-carbonate vein deposits are typically associated with iron-carbonate alteration. The relative timing of mineralization is syn- to late-deformation and typically post-peak greenschist-facies or syn-peak amphibolitefacies metamorphism. They are formed from low salinity, H2O-CO2-rich hydrothermal fluids with typically anomalous concentrations of CH4, N2, K, and S. Gold is mainly confined to the quartz-carbonate vein networks but may also be present in significant amounts within iron-rich sulphidized wall rock. Greenstone-hosted quartz-carbonate vein deposits are distributed along major compressional to transpressional crustal-scale fault zones in deformed greenstone terranes of all ages, but are more abundant and significant, in terms of total gold content, in Archean terranes. However, a significant number of world-class deposits (>100 t Au) are also found in Proterozoic and Paleozoic terranes. International examples of this subtype of gold deposits include Mt. Charlotte, Norseman, and Victory (Australia), Bulyanhulu (Tanzania), and Kolar (India) (Fig. 2). Canadian examples include Sigma-Lamaque (Québec), Dome and Pamour (Ontario), Giant and Con (Northwest Territories), San Antonio (Manitoba), Hammer Down (Newfoundland), and Bralorne-Pioneer (British Columbia). Detailed characteristics and references are found in the text below. The reader may refer to Appendix 1 for a list of geographical, geological, and economical characteristics of Canadian gold deposits with more than 250 000 oz Au in combined production and reserves (data from Gosselin and Dubé, 2005b).
Summary of Economic Characteristics
The total world production and reserves of gold, including the Witwatersrand paleoplacer deposits, stands at more than 126 420 metric tonnes Au (Gosselin and Dubé, 2005a). World production and reserves for the greenstone-hosted quartz-carbonate vein deposit subtype is 15 920 metric tonnes Au (Gosselin and Dubé, 2005a), which is equivalent to 13% of the total world production and puts them in second place for world productivity behind paleoplacers. Total Canadian production and reserves, at 9 280 metric tonnes Au, represent 7% of the world total. However, Canadian production and reserves for the greenstone-hosted quartz-carbonate vein subtype are 5 510 metric tonnes, which constitutes 35% of the world production for this deposit subtype, and 59% of the total Canadian production and reserves of gold. The Superior province contains 86% (4 760 metric tonnes) of Canadian gold production and reserves for greenstone-hosted quartzcarbonate vein deposits (Gosselin and Dubé, 2005a,b). The Abitibi sub-province is the main source and represents 81% (4 470 metric tonnes) of the total Canadian gold.
There are 103 known greenstone-hosted quartz-carbonate vein deposits world-wide containing at least 30 tonnes (~1 M oz) Au (production and reserves), including 31 Canadian deposits, whereas 33 other deposits in Canada, and several hundred worldwide, contain more than 7.5 tonnes (~250 000 oz) but less than 30 tonnes (Gosselin and Dubé, 2005b). A select group of 41 world-class deposits contains more than 100 tonnes Au, including 11 giant deposits with more than 250 tonnes. In this group of world-class deposits, six are from the Abitibi greenstone belt of the Canadian Archean Superior Province (Fig. 3). The Superior Province is the largest and best preserved Archean craton in terms of greenstone-hosted gold endowment, followed by the Yilgarn craton of Australia.
The temporal and geographic distribution of greenstonehosted quartz-carbonate vein deposits is shown on Figure 2. Greenstone-hosted quartz-carbonate vein deposits occur in greenstone terranes of all ages. Although they are present in Paleozoic to Tertiary terranes, they are mainly concentrated in Precambrian terranes, and particularly in those of late Archean age. In Canada, all the world-class deposits but one (Bralorne-Pioneer) are of late Archean age. Their concentration in the Archean is thought to be related to 1) continental growth and the related higher number of large-scale collisions between continental fragments (and/or arc complex), and 2) the associated development of major faults and largescale hydrothermal fluid flow during the supercontinent cycle and mantle plume activity (cf. Barley and Groves, 1992; Condie, 1998; Kerrich et al., 2000; Goldfarb et al., 2001).
Grade and Tonnage Characteristics
Greenstone-hosted quartz-carbonate vein deposits are second on total tonnage of gold only to the Witwatersrand paleoplacers of South Africa. The largest greenstone-hosted quartzcarbonate vein deposit in terms of total gold content is the Golden Mile complex in Kalgoorlie, Australia, with more than 1800 tonnes Au (Gosselin and Dubé, 2005a). The Hollinger- McIntyre deposit in Timmins, Ontario, is the second largest deposit of such type ever found with 987 tonnes Au (Gosselin and Dubé, 2005a). In contrast to the Golden Mile complex, open pit mining of the Hollinger-McIntyre deposit is now impossible due to housing, which leaves a significant part of the total gold content of the deposit inaccessible.
The average grade of greenstone-hosted quartz-carbonate deposits is fairly consistent, ranging from 5 to 15 g/t Au, whereas the tonnage is highly variable and ranges from a few thousand tonnes to over 100 million tonnes of ore, although more typically these deposits contain only a few million tonnes of ore (Fig. 4).
Comparison of Grade and Tonnage Characteristics with the Global Range
In Canada, this type of gold deposit is widely distributed from the Paleozoic greenstone terranes of the Appalachian Orogen on the east coast (e.g. Hammer Down and Deer Cove Newfoundland, Dubé et al., 1993; Gaboury et al., 1996), through the Archean greenstone belts of the Superior (Dome and Sigma-Lamaque) and Slave provinces (Con and Giant) in central Canada, to the oceanic terranes of the Cordillera (Bralorne-Pioneer).
The average gold grade of world-class Canadian deposits is 10 g/t, which is slightly higher than the average for this type of deposit worldwide (7.6 g/t, Fig. 5). World-class deposits in Canada have on average lower tonnage (20.91 Mt of ore) than those worldwide (39.91 Mt). Perhaps this is in part because mining in Canada has traditionally taken place underground, whereas in other countries open pits have also been developed.
Physical Properties
Mineralogy
The main gangue minerals in greenstone-hosted quartzcarbonate vein deposits are quartz and carbonate (calcite, dolomite, ankerite, and siderite), with variable amounts of white micas, chlorite, tourmaline, and sometimes scheelite. The sulphide minerals typically constitute less than 5 to 10% of the volume of the orebodies. The main ore minerals are native gold with, in decreasing amounts, pyrite, pyrrhotite, and chalcopyrite and occur without any significant vertical mineral zoning. Arsenopyrite commonly represents the main sulphide in amphibolite-facies rocks (e.g. Con and Giant) and in deposits hosted by clastic sediments. Trace amounts of molybdenite and tellurides are also present in some deposits, such as those hosted by syenite in Kirkland Lake (Thompson et al., 1950; Fig. 6A, B).
Textures
This type of gold deposit is characterized by moderately to steeply dipping, laminated fault-fill quartz-carbonate veins (Fig. 7A, B, C) in brittle-ductile shear zones and faults, with or without fringing shallow-dipping extensional veins and breccias (Fig. 7D, E). Quartz vein textures vary according to the nature of the host structure (extensional vs. compressional). Extensional veins typically display quartz and carbonate fibres at a high angle to the vein walls and with multiple stages of mineral growth (Fig. 7E), whereas the laminated veins are composed of massive, fine-grained quartz. When present in laminated veins, fibres are subparallel to the vein walls (Robert et al., 1994; Robert and Poulsen, 2001).
Dimensions
Individual vein thickness varies from a few centimetres up to 5 metres, and their length varies from 10 up to 1000 m. The vertical extent of the orebodies is commonly greater than 1 km and reaches 2.5 km in a few cases (e.g. the Kirkland Lake deposit, Charlewood, 1964).
Morphology
The gold-bearing shear zones and faults associated with this deposit type are mainly compressional and they commonly display a complex geometry with anastomosing and/or conjugate arrays (Daigneault and Archambault, 1990; Hodgson, 1993; Robert et al., 1994; Robert and Poulsen, 2001). The laminated quartz-carbonate veins typically infill the central part of, and are subparallel to slightly oblique to, the host structures (Hodgson, 1989; Robert et al., 1994; Robert and Poulsen, 2001) (Fig. 8). The shallow-dipping extensional veins are either confined within shear zones, in which case they are relatively small and sigmoidal in shape, or they extend outside the shear zone and are planar and laterally much more extensive (Robert et al., 1994).
Stockworks and hydrothermal breccias may represent the main mineralization styles when developed in competent units such as the granophyric facies of differentiated gabbroic sills (e.g. San Antonio deposit, Robert et al., 1994; Robert and Poulsen, 2001), especially when developed at shallower crustal levels. Ore-grade mineralization also occurs as disseminated sulphides in altered (carbonatized) rocks along vein selvages. Due to the complexity of the geological and structural setting and the influence of strength anisotropy and competency contrasts, the geometry of vein networks varies from simple (e.g. Silidor deposit), to fairly complex with multiple orientations of anastomosing and/or conjugate sets of veins, breccias, stockworks, and associated structures (Dubé et al., 1989; Hodgson, 1989, Belkabir et al., 1993; Robert et al., 1994; Robert and Poulsen, 2001). Layer anisotropy induced by stiff differentiated gabbroic sills within a matrix of softer rocks, or, alternatively, by the presence of soft mafic dykes within a highly competent felsic intrusive host, could control the orientation and slip directions in shear zones developed within the sills; consequently, it may have a major impact on the distribution and geometry of the associated quartz-carbonate vein network (Dubé et al., 1989; Belkabir et al., 1993). As a consequence, the geometry of the veins in settings with large competence contrasts will be strongly controlled by the orientation of the hosting bodies and less by external stress. The anisotropy of the stiff layer and its orientation may induce an internal strain different from the regional one and may strongly influence the success of predicting the geometry of the gold-bearing vein network being targeted in an exploration program (Dubé et al., 1989; Robert et al., 1994).
Host Rocks
The veins in greenstone-hosted quartz-carbonate vein deposits are hosted by a wide variety of host rock types; mafic and ultramafic volcanic rocks and competent iron-rich differentiated tholeiitic gabbroic sills and granitoid intrusions are common hosts. However, there are commonly district- specific lithological associations acting as chemical and/or structural traps for the mineralizing fluids as illustrated by tholeiitic basalts and flow contacts within the Tisdale Assemblage in Timmins (cf. Hodgson and MacGeehan, 1982; Brisbin, 1997). A large number of deposits in the Archean Yilgarn craton are hosted by gabbroic ("dolerite") sills and dykes (Solomon et al., 2000) as illustrated by the Golden Mile dolerite sill in Kalgoorlie (Bartram and McGall, 1971; Travis et al., 1971; Groves et al., 1984), whereas in the Superior Province, many deposits are associated with porphyry stocks and dykes (Hodgson and McGeehan, 1982). Some deposits are also hosted by and/or along the margins of intrusive complexes (e.g. Perron- Beaufort/North Pascalis deposit hosted by the Bourlamaque batholith in Val d'Or (Belkabir et al., 1993; Robert, 1994)). Other deposits are hosted by clastic sedimentary rocks (e.g. Pamour, Timmins).
Chemical Properties
Ore Chemistry
The metallic geochemical signature of greenstone-hosted quartz-carbonate vein orebodies is Au, Ag, As, W, B, Sb, Te, and Mo, typically with background or only slightly anomalous concentrations of base metals (Cu, Pb, and Zn). The Au/Ag ratio typically varies from 5 to 10. Contrary to epithermal deposits, there is no vertical metal zoning. Palladium is locally present as illustrated by the syndefor-mation auriferous quartz or hematite-quartz veins hosted by Proterozoic iron formation in Brazil (Olivo et al., 1995).
Alteration Mineralogy and Chemistry
At a district scale, greenstone-hosted quartz-carbonate vein deposits are associated with large-scale carbonate alteration (Fig. 9A, B) commonly distributed along major fault zones and associated subsidiary structures. At a deposit scale, the nature, distribution, and intensity of the wall-rock alteration is controlled mainly by the composition and competence of the host rocks and their metamorphic grade. Typically, the proximal alteration haloes are zoned and characterized – in rocks at greenschist facies – by iron-carbonatization and sericitization, with sulphidation of the immediate vein selvages (mainly pyrite, less commonly arsenopyrite). Altered rocks show enrichments in CO2, K2O, and S, and leaching of Na2O. Further away from the vein, the alteration is characterized by various amounts of chlorite and calcite, and locally magnetite (Phillips and Groves, 1984; Dubé et al., 1987; Roberts, 1987). The dimensions of the alteration haloes vary with the composition of the host rocks and may envelope entire deposits hosted by mafic and ultramafic rocks. Pervasive chromium- or vanadium-rich green micas (fuchsite and roscoelite) and ankerite with zones of quartzcarbonate stockworks are common in sheared ultramafic rocks (Fig. 9C, D). Common hydrothermal alteration assemblages that are associated with gold mineralization in amphibolite- facies rocks include biotite, amphibole, pyrite, pyrrhotite, and arsenopyrite, and, at higher grades, biotite/phlogopite, diopside, garnet, pyrrhotite and/or arsenopyrite (cf. Mueller and Groves, 1991; Witt, 1991; Hagemann and Cassidy, 2000; Ridley et al., 2000, and references therein), with variable proportions of feldspar, calcite, and clinozoisite (Fig. 10). The variations in alteration styles have been interpreted as a direct reflection of the depth of formation of the deposits (Colvine, 1989; Groves, 1993). The alteration mineralogy of the deposits hosted by amphibolite- facies rocks, in particular the presence of diopside, biotite, K-feldspar, garnet, staurolite, andalusite, and actinolite, suggests that they share analogies with gold skarns, especially when they (1) are hosted by sedimentary or mafic volcanic rocks, (2) contain a calc-silicate alteration assemblage related to gold mineralization with an Au-As-Bi-Te metallic signature, and (3) are associated with granodioritediorite intrusions (cf. Meinert, 1998; Ray, 1998). Canadian examples of deposits hosted in amphibolite-facies rocks include the replacement-style Madsen deposit in Red Lake (Dubé et al., 2000) and the quartz-tourmaline vein (Fig. 7F) and replacement-style Eau Claire deposit in the James Bay area (Cadieux, 2000; Tremblay, 2006).
Geological Properties
Continental Scale
Greenstone-hosted quartz-carbonate-vein deposits are typically distributed along crustal-scale fault zones (cf. Kerrich et al., 2000, and references therein) characterized by several increments of strain (e.g. Cadillac-Larder Lake fault) (Figs. 3, 11A, B, 12A, B), and, consequently multiple generations of steeply dipping foliations and folds resulting in a complex deformational history. These crustal-scale fault zones are the main hydrothermal pathways towards higher crustal levels. However, the deposits are spatially and genetically associated with second- and third-order compressional reverse-oblique to oblique brittle-ductile high-angle shear and high-strain zones (Fig. 12C), which are commonly located within 5 km of the first order fault and are best developed in its hanging wall (Robert, 1990). Brittle faults may also be the main host to gold mineralization as illustrated by the Kirkland Lake Main Break, a brittle structure hosting the giant Kirkland Lake deposit exploited by seven mines that have collectively produced more than 760 metric tonnes of gold (Fig. 13) (Thomson, 1950; Kerrich and Watson, 1984; Ayer et al., 2005; Ispolatov et al., 2005 and references therein). Greenstone-hosted quartz-carbonate vein deposits typically formed late in the tectonic-metamorphic history (Groves et al., 2000; Robert et al., 2005) and the mineralization is syn- to late-deformation and typically post-peak greenschist-facies and syn-peak amphibolite-facies metamorphism (cf. Kerrich and Cassidy, 1994; Hagemann and Cassidy, 2000). Most world-class greenstone-hosted quartzcarbonate vein deposits are hosted by greenschist-facies rocks. Important exceptions include Kolar (India), which formed at amphibolite facies.
Greenstone-hosted quartz-carbonate vein deposits are also commonly spatially associated with Timiskaming-like regional unconformities (Fig. 14A, B, C). Several deposits are hosted by, or located next to, such unconformities (e.g. the Pamour and Dome deposits), suggesting an empirical temporal and spatial relationship between large gold deposits and regional unconformities (Poulsen et al., 1992; Hodgson, 1993; Robert, 2000; Dubé et al., 2003; Robert et al., 2005).
District Scale
In this section, some of the key geological characteristics of prolific gold districts are presented with a special emphasis on Archean deposits. Only a brief overview is presented here, and the reader is referred to key papers by Hodgson and MacGeehan (1982), Hodgson (1993), Robert and Poulsen (1997), Hagemann and Cassidy (2000), Poulsen et al. (2000), Groves et al. (2003), and Robert et al. (2005), among others, for more information.
Large gold camps are commonly associated with curvatures, flexures, and dilational jogs along major compressional fault zones, such as the Porcupine-Destor fault in Timmins or the Larder Lake-Cadillac fault in Kirkland Lake (Fig. 3), which have created dilational zones that allowed migration of hydrothermal fluids (cf. Colvine et al., 1988; Sibson, 1990; Phillips et al., 1996; McCuaig and Kerrich, 1998; Hagemann and Cassidy, 2000; Kerrich et al., 2000; Groves et al., 2003; Goldfarb et al., 2005; Ispolatov et al., 2005; Robert et al., 2005). In terms of geological setting, large gold districts, such as Timmins, are mainly underlain by tholeiitic basalts (commonly variolitic) (Fig. 14D) and ultramafic komatiitic flows that are intruded by intermediate to felsic porphyries, and locally swarms of albitite and/or lamprophyre dykes (cf. Hodgson and MacGeehan, 1982). Irrelevant to their age, Timiskaming-like regional unconformities, distributed along major faults or stratigraphical dis-continuities, are also typical of large gold camps. In terms of hydrothermal alteration, the main characteristic at the district scale is the presence of large-scale iron-carbonate alteration, the width of which gives some indication as to the size of the hydrothermal system(s) (e.g. Timmins). Protracted magmatic activity with synvolcanic and syn- to late tectonic intrusions emplaced along structural discontinuities (e.g. Destor-Porcupine Fault) may also be highly significant. In many cases, U-Pb dating of intrusive rocks indicates that they are older than gold mineralization, in which case these rocks may have provided a competent structural trap or induced anisotropy in the layered stratigraphy that influenced and partitioned the strain. In other cases, the intrusive rocks are post-mineralization. However, the possibility remains that the thermal energy provided by some intrusions contributed to large-scale and long-lived hydrothermal fluid circulation (cf. Wall, 1989).
The presence of other deposit types in a district, such as volcanogenic massive sulphide (VMS) or Ni-Cu deposits, is also commonly thought to be a favourable factor (cf. Hodgson, 1993; Huston, 2000). The provinciality of the high Au content of a district may be related to specific fundamental geological characteristics in terms of favourable source-rock environments or gold reservoirs (Hodgson, 1993). The local geological "heritage" of the district, in addition to ore-forming processes, may thus be a major factor to take into account.
Knowledge Gaps at District Scale: One of the main remaining knowledge gaps at district scale is the structural evolution, and in some cases, the tectonic significance of the large-scale faults that control the distribution of the greenstone- hosted quartz-carbonate-vein deposits. The nature and significance of the early stage(s) of deformation (e.g. D0- D1) of major fault zones to the circulation of gold-bearing fluids and the formation of large gold deposits remain obscure. For example, despite decades of work in the Timmins' district, the structural evolution of the Porcupine- Destor Fault, a poorly exposed, regionally extensive, steeply dipping, long-lived fault (active between ca. 2680-2600 Ma), and its definite relationship to gold mineralization, remain controversial (cf. Hurst, 1936; Pyke, 1982; Bleeker, 1995; 1997; Hodgson and Hamilton, 1989; Hodgson et al., 1990; Brisbin, 1997; Ayer et al., 2005; Bateman et al., 2005, and references therein). The processes controlling the distribution of the large gold districts along such crustal-scale structures are poorly understood and therefore remain an avenue for future research (Robert et al., 2005). Key questions remain, such as the reason(s) why the Timmins district contains a large number of world-class gold deposits, why some large-scale Archean fault zones in greenstone belts are devoid of significant gold deposits, and why the gold grade in some districts is significantly higher.
Deposit Scale
The location of higher grade mineralization (ore shoots) within a deposit has been the subject of investigation since the early works of Newhouse (1942) and McKinstry (1948). Ore shoots represent a critical element to take into account when defining and following the richest part of an orebody. Two broad categories of ore shoots are recognized: 1) geometric, and 2) kinematic (Poulsen and Robert, 1989; Robert et al., 1994; Robert and Poulsen, 2001). As outlined by Poulsen and Robert (1989), geometric ore shoots are controlled by the intersection of a given structure (i.e., a fault, a shear zone, or a vein) with a favourable lithological unit, such as a competent gabbroic sill, a dyke, an iron formation, or a particularly reactive rock. The geometric ore shoot will be parallel to the line of intersection. The kinematic ore shoots are syndeformation and syn-formation of the veins, and are defined by the intersection between different sets of veins or contemporaneous structures. The plunge of kinematic ore shoots is commonly at a high angle to the slip direction.
Structural traps, such as fold hinges or dilational jogs along faults or shear zones, are also key elements in locating the richest part of an orebody. However, multiple factors are commonly involved, as mentioned by Groves et al. (2003), and world-class and giant-size deposits commonly exhibit complex geometries. This complexity is mainly due to the longevity of the hydrothermal system and/or multistage, barren and/or gold-bearing hydrothermal, structural, and magmatic events (Dubé et al., 2003; Groves et al., 2003; Ayer et al., 2005). This is especially well illustrated at the Dome mine, where low-grade colloform-crustiform ankerite veins cut the 2690 ± 2 Ma Paymaster porphyry (Corfu et al., 1989) (Fig. 15A). These ankerite veins have been deformed; they are typically boudinaged and are cut by extensional, en echelon, auriferous quartz veins (Fig. 15B, C). The <2673.9 ± 1.8 Ma Timiskaming conglomerate (Ayer et al., 2003, 2005) contains clasts of the ankerite veins in the Dome open pit (Fig. 15D, E), whereas the Timiskaming conglomerate is itself carbonatized, cut by auriferous quartz veins and locally contains spectacular visible gold (Fig. 15F). Argillite and sandstone above the Timiskaming conglomerate are themselves folded and cut by auriferous quartz veins (Dubé et al., 2003). These chronological relationships illustrate the superimposed hydrothermal and structural events involved in the formation of the giant deposit with post-magmatic carbonate veining predating the deposition of the Timiskaming conglomerate, which in turn precedes formation of the bulk of the gold mineralization.
The most productive Canadian metallogenic districts for greenstone-hosted quartz-carbonate vein deposits occur in (Late) Archean greenstone belts of the Superior, Churchill, and Slave provinces (Table 1). The Abitibi greenstone belt contains the majority of the productive districts, including the very large Timmins, Kirkland Lake, Larder Lake, Rouyn-Noranda, and Val d'Or districts. The Kirkland Lake gold deposit is included here as a greenstone-hosted quartzcarbonate deposit, however, the structural timing of gold deposition and its origin is still the subject of debate (Kerrich and Watson, 1984; Cameron and Hattori, 1987; Robert and Poulsen, 1997; Ayer et al., 2005; Ispolatov et al., 2005) as the deposit shares strong analogies with tellurium-rich syndeformation gold deposits associated with alkaline magmatism as defined by Jensen and Barton (2000). Other younger greenstone belts of the Appalachian and Cordilleran orogens are also favourable terranes for quartz-carbonate vein-type gold deposits (Fig. 16). Districts listed in Table 1 also include deposits hosted by iron formation (BIF-hosted vein or Homestake-type; Poulsen et al., 2000).
The geographical and temporal distribution of greenstonehosted quartz-carbonate vein deposits containing at least 30 t Au is included in Figure 2. The greatest concentration of deposits is found in the Archean, particularly in the Late Archean in Canada (Fig. 16). Proterozoic gold deposits occur in the United States as exemplified by the Homestake deposit, a giant iron-formation-hosted vein and disseminated Au-Ag deposit, as well as in greenstone belts of Brazil and western Africa. However, Canadian deposits of Proterozoic age are rare; they include the New Britannia deposit in the Flin Flon district (Manitoba) and other smaller deposits of the Churchill Province, as well as gold-bearing quartz-carbonate veins in the central metasedimentary belt of the Grenville Province (Carter, 1984; Jourdain et al., 1990; Easton and Fyon, 1992). Mesozoic and Cenozoic deposits are less common, but are important within Circum-Pacific collisional orogenic belts (e.g. the Mesozoic Mother Lode and Alleghany districts, and the Cenozoic Alaska-Juneau and Treadwell deposits, USA). The only world-class Mesozoic Canadian deposit (Fig. 16) is the Bralorne-Pioneer deposit (British Columbia). Other smaller deposits (not represented in Fig.16) were also formed in the Cordilleran during the Mesozoic, and in the Appalachians during Paleozoic times.
Additionally, three important unexploited deposits (as of December 31, 2004) are noted on Figure 16:
The following deposits, which are located inside districts represented on Figure 16, also contain important unmined resources (as of December 31, 2004, unless otherwise indicated):
Associated Mineral Deposit Types
Greenstone-hosted quartz-carbonate vein deposits are thought to represent the main component of the greenstone deposit clan (Fig. 1) (Poulsen et al., 2000). However, in metamorphosed terranes, other types of gold deposits formed in different tectonic settings and/or crustal levels, such as Au-rich VMS or intrusion-related gold deposits, may have been juxtaposed against greenstone-hosted quartz-carbonate vein deposits during the various increments of strain that characterize Archean greenstone belts (Poulsen et al., 2000). Although these different gold deposits were formed at different times, they now coexist along major faults. Examples include the Bousquet 2 - Dumagami and LaRonde Penna Au-rich VMS deposits that are distributed a few kilometres north of the Cadillac-Larder Lake fault east of Noranda (Fig. 3), where the fault zone hosts the former O'Brien and Thompson Cadillac greenstone-hosted quartzcarbonate vein deposits. Intrusion-related syenite-associated disseminated gold deposits, such as the Holt-McDermott and Holloway mines in the Abitibi greenstone belt of Ontario, occur mainly along major fault zones, in association with preserved slivers of Timiskaming-type sediments and consequently are spatially associated with greenstone-hosted quartz-carbonate vein deposits (Robert, 2001).
Poulsen et al. (2000) has indicated that one of the main problems in deformed and metamorphosed terranes, such as those underlain by greenstone belts, is that many primary characteristics may have been obscured by overprinting deformation and metamorphism to the extent that they are difficult to recognize. This is particularly the case with goldrich VMS or intrusion-related deposits. But since greenstone- hosted quartz-carbonate vein deposits are syn- to late main phase of deformation, their primary features are, in most cases, relatively well preserved (Groves et al., 2000). Consequently, once a deposit is appropriately classified, exploration models are relatively well defined (cf. Hodgson, 1990, 1993; Groves et al., 2000, 2003). Since the early 1980s, several different genetic models have been proposed to explain the formation of greenstone-hosted quartz-carbonate vein deposits and this has resulted in significant controversy. Some of this controversy is caused by the difficulty in metamorphosed greenstone terranes to classify certain key deposits, such as Hemlo (Lin, 2001; Muir, 2002; Davis and Lin, 2003), due to the poor preservation of primary characteristics largely obscured by post-mineralization deformation and metamorphism. Thus, adequate classification of gold deposits is a key to formulating successful exploration models (Poulsen et al., 2000). An excellent review of the various proposed genetic models, and the pros and cons of each of these, has been presented by Kerrich and Cassidy (1994). Since then, Hagemann and Cassidy (2000), Kerrich et al. (2000), Ridley and Diamond (2000), Groves et al. (2003), and Goldfarb et al. (2005), among others, have also revisited the subject. Only a brief summary is presented here.
Several genetic models have been proposed during the last two decades without attaining a definite consensus. One of the main controversies is related to the source of the fluids. The ore-forming fluid is typically a 1.5 ± 0.5 kb, 350 ± 50°C, low-salinity H2O-CO2 ± CH4 ± N2 fluid that transported gold as a reduced sulphur complex (Groves et al., 2003). Several authors have emphasized a deep source for gold, with fluids related to metamorphic devolatilization, and deposition of gold over a continuum of crustal levels (cf. Colvine, 1989; Powell et al., 1991; Groves et al., 1995). Others have proposed a magmatic source of fluids (cf. Spooner, 1991), a mantle-related model (Rock and Groves, 1988), drifting of a crustal plate over a mantle plume (Kontak and Archibald, 2002), anomalous thermal conditions associated to upwelling asthenosphere (Kerrich et al., 2000), or deep convection of meteoric fluids (Nesbitt et al., 1986). Hutchinson (1993) has proposed a multi-stage, multiprocess genetic model in which gold is recycled from preenriched source rocks and early formed, typically subeconomic gold concentrations. Hodgson (1993) also proposed a multi-stage model in which the gold was, at least in part, recycled from gold-rich district-scale reservoirs that resulted from earlier increments of gold enrichment.
The debate on gold genesis was, at least in part, based upon interpretations of stable isotope data, and after more than two decades, it is still impossible to unequivocally distinguish between a fluid of metamorphic, magmatic, or mantle origin (Goldfarb et al., 2005). The significant input of meteoric waters in the formation of quartz-carbonate greenstone- hosted gold deposits is now, however, considered unlikely (Goldfarb et al., 2005). The magmatic and mantlerelated models mainly based on spatial relationships between the deposits and intrusive rocks, are challenged by crosscutting field relationships combined with precise U-Pb zircon dating. These show that, in most cases, the proposed magmatic source for the ore-forming fluid is significantly older than the quartz-carbonate veins. For example, in the Timmins area, the quartz-carbonate veins hosting the gold mineralization at the Hollinger-McIntyre deposit cut an albitite dyke intruding the Pearl Lake porphyry (Fig. 17). One such albitite dyke was dated at 2673 +6/-2 Ma (Marmont and Corfu, 1989) and more recently at 2672.8 ± 1.1 Ma (Ayer et al., 2005). Thus the albitite dyke is ca.15 Ma younger than the 2689 ± 1 Ma Pearl Lake porphyry and various porphyries in the regions ranging in age from 2691 to 2687 Ma (Corfu et al., 1989; Ayer et al., 2003). These chronological relationships rule out the possibility that the ore fluids could be related to known intrusions. An alternative to the magmatic fluid source model is one in which intrusions have provided the thermal energy responsible, at least in part, for fluid circulation (cf. Wall, 1989). The mantle- related model was mainly based on the close spatial relationship between lamprophyre dykes and gold deposits (Rock and Groves, 1988). Key arguments against such a model have been presented by Wyman and Kerrich (1988, 1989). Recently, Dubé et al. (2004) have demonstrated that the lamprophyre dykes spatially associated with gold mineralization at the Campbell-Red Lake deposit, although different than the typical greenstone-hosted quartz-carbonate vein deposit, are at least 10 Ma younger than the main stage of gold mineralization.
Each of these models has merit, and various aspects of all or some of them are potentially involved in the formation of quartz-carbonate greenstone-hosted gold deposits in metamorphic terranes. However, the overall geological settings and characteristics suggest that the greenstone-hosted quartz-carbonate vein deposits are related to prograde metamorphism and thermal re-equilibration of subducted volcano- sedimentary terranes during accretionary or collisional tectonics (cf. Kerrich et al., 2000, and references therein). The deep-seated, Au-transporting fluid has been channelled to higher crustal levels through major crustal faults or deformation zones (Figs. 1, 18). Along its pathway, the fluid has dissolved various components, notably gold, from the volcano- sedimentary packages, which may include a potential gold-rich precursor. The fluid will then precipitate sulphides, gold, and gangue minerals as vein material or wall-rock replacement in second- and third-order structures at higher crustal levels through fluid-pressure cycling processes (Sibson et al., 1988) and temperature, pH, and other physicochemical variations.
Nevertheless, the source of the ore fluid, and hence of gold in greenstone-hosted quartz-carbonate vein deposits, remains unresolved (Groves et al. 2003). According to Ridley and Diamond (2000), a model based on either metamorphic devolatilization or granitoid magmatism best fits most of the geological parameters. These authors indicated that the magmatic model could not be ruled out simply on the basis of a lack of exposed granite in proximity of a deposit with a similar age, because the full subsurface architecture of the crust is unknown. Ridley and Diamond (2000) also indicated that the fluid composition should not be expected to reflect the source. The fluid travels great distances and its measured composition now reflects the fluidrock interactions along its pathway, or a mixed signature of the source and the wall rocks (Ridley and Diamond, 2000).
In terms of exploration, at the geological province or terrane scale, geological parameters that are common in highly auriferous volcano-sedimentary belts include 1) reactivated crustal-scale faults that controlled emplacement of porphyry- lamprophyre dyke swarms; 2) complex regional-scale geometry of mixed lithostratigraphic packages; and 3) evidence for multiple mineralization or remobilization events (Groves et al., 2003). The empirical spatial and potentially genetic (?) relationship between large gold deposits and a Timiskaming-like regional unconformity represents a key first-order exploration target irrelevant to the deposit type or the mineralization style, as illustrated by large gold districts such as Timmins, Kirkland Lake, and Red Lake (Poulsen et al., 1992; Hodgson, 1993; Robert, 2000; Dubé et al., 2000, 2003, 2004; Robert et al., 2005).
Several outstanding problems remain for greenstonehosted quartz-carbonate vein deposits. As mentioned above, the sources of fluid and gold remain unresolved (Ridley and Diamond, 2000). Other critical elements are listed in Hagemann and Cassidy (2000) and Groves et al. (2003). In practical terms, the three most outstanding knowledge gaps to be addressed are
The classification of gold deposit types remains a problem, which is more than an academic exercise as it has a major impact on exploration strategies (e.g. what type of deposit to look for, where, and how?) (Poulsen et al., 2000). However, the reasons why geological provinces, such as the Superior province and the Yilgarn craton are so richly endowed are now much better understood (Robert et al., 2005). It is also believed that integrated research programs, such as the Geological Survey of Canada EXTECH, Natmap, or Targeted Geoscience Initiative, where various aspects of the geology of a gold mining district or camp are addressed, remain an excellent approach for developing additional understanding of these deposits. The most fundamental elements to take into account to successfully establish the complex evolution and relationships between mineralizing event(s), geological setting, and deformation/metamorphism phase(s) are
This synthesis has been made possible by the kind cooperation of numerous company, government, and university geologists who shared their knowledge and who have allowed surface and underground visits to many gold deposits. We benefited from numerous discussions with colleagues from the provincial surveys and from the Geological Survey of Canada. The first author would like to extend his deepest appreciation to F. Robert and H.K. Poulsen for constructive suggestions, collaboration, and discussions on gold deposits during the last twenty years. W. Goodfellow and I. Kjarsgaard are thanked for their editorial contribution. Careful constructive reviews by R. Goldfarb, M. Gauthier, and S. Castonguay have led to substantial improvements.
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xls version [XLS, 17.9 kb]
| District | Geological Province | Production & Reserves (tonnes Au)* | Resources (tonnes Au)* |
|---|---|---|---|
| Timmins | Superior/Abitibi | 2,072.9 | 78.5 |
| Kirkland Lake | Superior/Abitibi | 794.8 | 72.6 |
| Val d'Or | Superior/Abitibi | 638.9 | 171.6 |
| Rouyn-Noranda | Superior/Abitibi | 519.6 | 66.5 |
| Larder Lake | Superior/Abitibi | 378.7 | 14.5 |
| Malartic | Superior/Abitibi | 278.7 | 686.8 |
| Red Lake** | Superior/Uchi | 128.0 | 17.2 |
| Joutel | Superior/Abitibi | 61.4 | 27.5 |
| Matheson | Superior/Abitibi | 60.4 | 9.7 |
| Cadillac | Superior/Abitibi | 22.1 | 25.1 |
| Pickle Lake | Superior/Uchi | 90.4 | 8.1 |
| Rice Lake | Superior/Uchi | 51.6 | 25.2 |
| Beardmore-Geraldton | Superior/Wabigoon | 123.5 | 35.1 |
| Michipicoten | Superior/Wawa | 41.1 | 2.8 |
| Mishibishu | Superior/Wawa | 26.7 | 16.8 |
| Goudreau-Lolshcach | Superior/Wawa | 8.8 | 19.6 |
| Flin Flon | Churchill | 62.2 | 12.7 |
| Lynn Lake | Churchill | 19.5 | 14.6 |
| La Ronge | Churchill | 3.4 | 5.6 |
| Keewatin | Churchill-Hearne | 7.2 | 252.4 |
| Yellowknife | Slave | 432.8 | 16.6 |
| MacKenzie | Slave | 38.1 | 286.6 |
| Cassiar | Cordillera | 14.9 | 55.4 |
| Baie Verte | Appalachian/Dunnage | 10.3 | 8.9 |
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*as of December 31, 2002 **does not include the Campbell-Red Lake, Cochenour and MacKenzie Red Lake deposits as they are not considered typical GQCV deposits |
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